Method of @@@-alkanes oxidation
专利摘要:
Alkanes are oxidized in the liquid phase at relatively low temperature using heteropolyacids or polyoxoanions promoted with azide or certain metals. Such azide catalysts are also part of the invention. 公开号:SU1766248A3 申请号:SU884356231 申请日:1988-07-19 公开日:1992-09-30 发明作者:Е.Эллис Мл Пол;Е.Лайонз Джеймс;К.Майерз Мл Хэрри;Салд Джордж;А.Лэнгдэйл Вейн 申请人:Сан Рифайнинг Энд Маркетинг Компани; IPC主号:
专利说明:
Etc /; vi o; G1olu en -: e XsPW 1Р: е 2-1) Oz. 15.0 Г 12-СОЛг, ф05К-ОФССфОСНОЙ СИС ЮТс 35 ml of the zodine is dissolved. When paoemeshiv-nii ustanazl uuyut pi-i psi pomosch: 5i; -:.: ..:; . 00: ZTZ Natrium DKO / -J 5 2. But:;. hzGREBZ - g j-V-HrO. COP ii ;; r. yr;, g: -; - t-j; o; / g: 7.Ps /.--. e.i,: / t-,: -i - i r. ; C42. : - - ---: 20, 0 .-: EG -.- YOCH-glufoophos: -. ; x /:;: /; STY J OP; --.- ..;. ;;. . .:. g J -., -; --J .- -. . :. - -. ..-: V: .-:,. .. . :. .. -; j с у Go -a: go: 1 ops. ::: -; / PI POSG. 5H5. tr. - -VOKO l T G uSL -Idl j Я6Т JUICE Cj С 1 ф .. v & Oi zyostys 40% 1 and fdTO-i ft net, r IBI-. - h -, -,, ju%) os Trime o 43 Lnalo uCh | -1 titer hO./Toury-syvyu- L tropeg are oxidized from ecetonitrile can be used in the presence of hgPW hPeOzMh From mmol to mole sent; Semi-div, g 231 can / h product feeds / puts on itself Gs-alcohol | selek lvogt Zg% and e to ic 64% potential) C., l Example 4/1 MOOPZN Yu1 6 H inti p -s 150 ° C Use the following kata v3r- o l i tori (each in the amount of v. Mviole j "with Pa mol 1 g) K4NbA / 0 j P- (, NI-U) 6p2WiB062 & J K PReVV, re grogon as u1 / h zopropanol and / ix is obtained from this.} in on v has j /. / 000 mog / h with septicity y50 ° n-sp g t and UTB / in the mean. 6j gs 2 (mop / h with the help of 8% ric 1 uki) 1% lg at sleep ° zu at choli-260C - t i -ch. / - with 4% and 55% with pech4e jr the sho Example 45 I eksana oxide osu y. ten Noah sour as solvent in HI j 61 Poi 100 ° C Use CNT blowing dTj id ery in sflv O-M ix save ff to v j rph „acha) p.1 К6Ь сОО о О О G, Kqn D6V00 0 0 i D) K, GO-, 0 Proa / kg receive in sted SPP3 sdetectnosy, i o i and hu ke ichu 6 bb and 5 cooTneTCiac IH / r g and f, C j Jt PO If ° t --0 1 3Ј COUNTER IS TYE 10 It / I Cbo 31gs com-a noi pagrevanig p04s / and ayut 4 hours Rohz ih CTL K-ag r n j ibp 14 I1 o and m - o / | oluna-o p ie / poo n, csr o nf., pe D j " r i t, ICO С and voe v realz and L e i, since what time and tag AZ Time can OLI.C, i-a U m / "-, m / oo / ioue d temperature o / h oi j i -i e belTb Or OMNATYO / 30 POZO JPPh T "-dri3 / ZKIM ObpaSONi / ja METHOD BL GS selectively results when oxidized - and thus about new to alcohols and ketsnam TL ie c-poric in The village of Ti5n011L (which defines n iv, t p as the percentage of prorezgirozawa i GO 3 CM CO CD about e LO t
权利要求:
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引用文献:
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申请号 | 申请日 | 专利标题 US07/076,570|US4803187A|1987-07-20|1987-07-20|Alkane oxidation catalysts| 相关专利
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